Product ID:FRESH PARA BLOCKS & CRYSTALS 12-4BB
MSDS Date:08/14/1989
FSC:6840
NIIN:00-664-6610
MSDS Number: BKSSP

FRESH PRODUCTS, INC.

4010 SOUTH AVE.
TOLEDO, OH 43615
US

Emergency Phone: 419-531-9741

Info Phone: 419-531-9741

Cage: EO672

FRESH PRODUCTS, INC.

TOLEDO, OH 43615

Telephone: (419) 531-9741

Cage: EO672

P-DICHLOROBENZENE (1,4-DICHLOROBENZENE) (SARA III)

CAS: 106-46-7

RTECS: CZ4550000

Fraction By Weight: 99.75%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM,A3 9394

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

CAS NOS. NOT AVAILABLE FOR FRAGRANCES SINCE THEY ARE

RTECS: 9999999ZZ

Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INGESTION AS ROUTE OF ENTRY IS
UNLIKELY. INHALATION OR INGESTION OF PARADICHLOROBENZENE AT
CONCENTRATIONS WELL ABOVE PERMISSIBLE EXPOSURE LIMITS CAN CAUSE
DEPRESSION OF COMMON NERVOUS SYSTEM, VAPOR MA Y CAUSE IRRITATION OF
SKIN OR EYES & HAS BEEN KNOWN TO CAUSE LIVER DAMAGE IN RATS &
RABBITS.
Effects of Overexposure:HEADACHE, DIZZINESS, EYES, NOSE & THROAT
IRRITATION, NAUSEA, FEELING OF DRUNKENESS & CARDIAC SENSITIZATION
MAY BE EXPERIENCED BY SOME INDIVIDUALS WHERE THE CONCENTRATION OF
PARA IS WELL ABOVE THE TLV IN CONFINED, POORLY VENTILATED AREAS.

First Aid:EYES:FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
SKIN:WASH AFFECTED AREA WITH SOAP & WATER. INHALED:REMOVE TO FRESH
AIR. IF SWALLOWED:RINSE MOUTH. DO NOT INDUCE VOMITING. GIVE LOTS OF
WATER OR MILK. IN ALL CASES WHERE PAIN IN AN AFFECTED AREA
PERSISTS, CALL A PHYSICIAN.

Flash Point Method:TCC
Flash Point:150 F/66 C
Lower Limits:2.5
Extinguishing Media:WATER SPRAY, FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING & NIOSH/MSHA APPROVED
SELF-CONTAINED BREATHING APPARATUS WHERE EXPOSURE TO VAPORS IS
POSSIBLE.

Spill Release Procedures:SCOOP UP & PUT IN CLOSED CONTAINER. KEEP
MATERIAL OUT OF SEWERS OR OPEN WATERWAYS. ALLOW SMALL AMOUNTS TO
EVAPORATE NATURALLY.

Handling and Storage Precautions:STORE AWAY FROM HEAT & OPEN FLAMES IN
TIGHTLY CLOSED CONTAINERS. AVOID EXCESSIVE INHALATION & CONTACT
WITH SKIN & EYES.
Other Precautions:DO NOT WEAR CONTACT LENSES WHEN HANDLING.

Respiratory Protection:IF AIRBORNE LIMITS MAY BE EXCEEDED, USE NIOSH
APPROVED RESPIRATOR
Ventilation:LOCAL EXHAUST:USE IN WELL VENTILATED AREAS.
Protective Gloves:NONE
Eye Protection:DO NOT RUB EYES WITH CONTAMINATED HAND
Other Protective Equipment:NONE
Work Hygienic Practices:WASH THOROUGHLY WITH SOAP & WATER AFTER COMING
IN CONTACT WITH PRODUCT
Supplemental Safety and Health
KEEP OUT OF REACH OF CHILDREN. MAY BE FATAL IF SWALLOWED. DO NOT BREATH
VAPOR OR DUST.

HCC:F4
Boiling Pt:B.P. Text:345F,174C
Melt/Freeze Pt:M.P/F.P Text:127F,53C
Vapor Pres:0.6
Vapor Density:5.1
Spec Gravity:1.245-1.250
Solubility in Water:.008
Appearance and Odor:WHITE BLOCK OR CRYSTALS "MOTHBALL" ODOR

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, HOT ALUMINUM & ALUMINUM ALLOYS
Stability Condition to Avoid:KEEP AWAY FROM OPEN FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
SMOKES, SOOT, HYDROGEN CHLORIDE & PHOSGENE.

Waste Disposal Methods:THE MATERIAL SHOULD BE BURNED IN AN APPROVED
INCINERATOR OR DISPOSE OF IN AN APPROVED WASTE DUMP IN ACCORDANCE
WITH APPLICABLE FEDERAL, STATE & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.